| Byakuya Kuchiki |
Do "Byakuya's Cooperation" in free time, or beat him in Bleach tower, Level 9 |
| Gin Ichimaru |
Beat him in 5 turns (before Izuru) in Bleach Tower, Level 6 |
| Hanatarou Yamada |
Do "Hanatarou's Cooperation" in free time, or beat him in Bleach Tower, Level 7 |
| Hinamori Momo |
Do "Hinamori's Cooperation" in free time, or beat her in Bleach Tower, Level 8 |
| Izuru Kira |
Do "Izuru's Cooperation" in free time, or beat him in Bleach Tower, Level 6 |
| Kaname Tousen |
Beat him in Bleach Tower, Level 12 |
| Renji Abarai |
Do "Renji's Cooperation" in free time, or beat him in Bleach Tower, Level 9 |
| Retsu Unohana |
Do "Unohana's Cooperation" In free time, or beat her in Bleach Tower, Level 7 |
| S. G. Yamamato |
Do "Yamamato's Cooperation" In free time, or beat him in Bleach Tower, Level 4 |
| Sajin Komamura |
Do "Komamura's Cooperation" In free time, or beat him in Bleach Tower, Level 10 |
| Shaolin Fong (Soi Fon) |
Do "Soi fon's Cooperation" in free time, or beat her in Bleach Tower, Level 5 |
| Shunsui Kyoraku |
Do "Kyoraku's Cooperation" in free time, or beat him in Bleach Tower, Level 11 |
| Shuuhei Hisagi |
Do "Hisagi's Cooperation" in free time, or beat him in Bleach Tower, Level 12 |
| Yoruichi Shihouin (Current) |
Do "Yoruichi's Cooperation" in free time, or beat her in Bleach Tower, Level 5 |
| Yoruichi Shihouin (Former) |
Beat her in Bleach Tower, in the level she's in with Kisuke Urahara |
