When picking your character at the selection screen, hold L1 + R1.
| Neji Hyuuga
||Beat story mode with anybody
| Hinata Hyuuga
||Beat story mode with Neji Hyuuga
||Beat story mode with Hinata Hyuuga
| Zabuza Momochi
|| Beat story mode with Haku
||Beat story mode with Zabuza Momochi
||Beat story mode with Gaara
| Cursed Sealed Sasuke
||Reach Chunin rank in Mission mode
||Reach Jonin rank in Mission mode
|| 50 exp. points
||500 exp. points
| Special Jonin
||1,150 exp. points
||1,750 exp. points
||2,170 exp. points
|| 2,490 exp. points
These unlock the first S-rank mission.
|44 Forest of Death (foreground)
||Hit the left fish 3 times
||Stand on the boat for 3 seconds
|Chunnin Testing Stage (foreground)
||Run through the tunnel from left to right 3 times
|Hero's Gravestone (any)
||Hit your opponent's support character 5 times
|Hokage's Statue Stage (foreground)
||Jump repeatedly on the tree to the left
|Nightly Rooftop Map (background)
||Stand on the tail of the right fish statue until the scroll appears
|Ramen Shop (foreground)
||Hit all the lanterns until they glow red
|Survival Stage (background)
||Destroy the doll on the right 10 - 15 times
|Tornado Sand Map (background)
||Destroy 8 objects flying in the tornado
|Wind Clan (foreground)
||Keep attacking the vending machine until the scroll shows up
|Yagura map with the Giant Frog & Snake (background)
||Jump from the top of the frog to the snake, then jump back
|Zabuza's Home (background)
||Stand on the balcony for 3 seconds
Finish Gaara's Story mode to unlock 2 Village of Sand missions, Kazekage's Mansion, Sumanigo Estate and Buddha Statue.
Finish Haku's Stroy mode to unlock Great Naruto Bridge and Zabuza's Hideout missions.
Reach Chunin rank to unlock the Collector's Capsule Machine. Also, reaching Anbu rank unlocks the Maniac's Capsule Machine.
Thanks to Revolution Readers mooboo, mmmhhmmm, KAYTER, Brokeas!